PCTU them Mendeleev organic chemistry. Department of Organic Chemistry and High Molecular Couplings

This is one of the oldest departments of the Chemical Faculty, founded in 1869. Outstanding chemists worked here, whose names are glory russian science - A.M. Butlers, N.A. Menshutytkin, A.E. Favorsky, S.V. Lebedev. In the post-revolutionary years, the Department was led by Professor Konstantin Aleksandrovich Tapale, Boris Nikolayevich Dolgov, Ivan Alexandrovich Diakonov, Konstantin Alexandrovich Ogloblin, Anatoly Alekseevich Potekin, who made a major contribution to development organic chemistry.

Since 2007, the Department has been headed by Professor Mikhail Anatolyevich Kuznetsov.

Department of Organic Chemistry Nowadays

Currently, an educational process at the Department of Organic Chemistry lead 8 professors (to which, in principle, add the director of the Institute of Chemistry I.A. Balov), 9 associate professors, 2 senior teachers and 4 assistant. Among the teachers and staff, the Department of 10 people have a doctorate degree of chemical sciences, 18 - degree of candidate of science. Academic work Departments include general courses and workshops on organic chemistry, introducing into spectroscopy, lectures on physical research methods organic substances and stereochemistry organic compounds, as well as special courses on various sections of synthetic and analytical organic chemistry for masters and graduate students.

The department prepares bachelors and masters in two specializations: general and synthetic organic chemistry, as well as analytical organic chemistry, and is actively involved in the preparation of graduates within the framework of interferedic specialization - environmental chemistry. Each year, the department finishes about 20 bachelors and masters. Every year there are 4-8 graduate students, most of which are successfully defended by the candidate dissertations. Graduates of the Department are in great demand in the labor market both in Russia and abroad. Teachers, employees, students and graduate students of the Department are actively involved in international scientific cooperation. Good scientific contacts Fixed with Universities in Germany (Karlsruhe, Leipzig, Ulm), Austria (Graz), France (Marseille, Strasbourg), USA (Buffalo, Bowling Green, Los Angeles).

Modern scientific topics Department of Organic Chemistry has strong historical roots. Here, first of all, it should be noted the leading start from the works of A.E. Favorsk research in the field of functionalized acetylene and diacetyl derivatives, which are now intensively conducted in groups of prof. I.A. Balova and A.V. Vasilyeva. Pioneer work prof. I.A. Dyaconov in chemistry of diazo compounds, carbenov, small cycles found their continuation and development in the works of Professors M.A. Kuznetsova, A.P. Molchanova, V.A. Nikolaev, M.S. Novikova, A.F. Khlebnikov and their disciples. Heritage prof. B.V. Ioffe in the field of chemistry of organic hydrazine derivatives, chemicals of heterocyclic compounds are developed by prof. MA Kuznetsov, D.Kh.n., Doc. V.V. Sokolov, and his analytical subjects multiplied by the works of prof. IG Zenkevich and L.A. Cartzova.

According to the results scientific activity Teachers, employees, students and graduate students of the Department annually published about 100 articles in leading international and domestic journals, dozens of abstracts of reports at international and All-Russian conferences. On the basis of the department regularly held All-Russian and international conferences on actual problems Organic Chemistry, including Youth Conferences with Wide International Participation. Scientific development The departments are supported by GRANTS RFF, RFBR, Presidential grants, Government of St. Petersburg, international grants. Teachers of the Department have repeatedly received prestigious Awards of St. Petersburg University "for pedagogical skill"(A.A. Kartzova, 2005, M.A. Kuznetsov, 2009, M.S. Novikov, 2012) and for the best scientific work (A.F. Khlebnikov, 2011).

The main directions of scientific research

• Chemistry of unforeseen and tense carbo- and heterocyclic systems. Carbenis, diazo compounds, small cycles (azirina, azridines, diaziridines, cyclopropanes, cyclopropines, triangulans), frame and spiospeted structures, 1,3-dipoles, cycling compound reactions. D.H.N. prof. MA Kuznetsov, A.P. Molchanov, M.S. Novikov, A.F. Khlebnikov, Ph.D., Doc. A.S. Konev, N.V. Rostov, A.S. Pankova, A.V. Stepakov, K.Kh.n., Art. Pre .. O.A. Tomashenko, K.Kh.n., Ass. HER. Galenko, M.M. Efremova, K.Kh.n. TA Cornilova.
• Chemistry of reactive intermediate sextial particles, diazo compounds and or emissions. Diazocarbonyl and diazodicarbonyl compounds. Photochemistry. D.H.N., prof. MA Kuznetsov, A.P. Molchanov, V.A. Nikolaev, M.S. Novikov, A.F. Khlebnikov, Ph.D., Doc. A.S. Konev, A.S. Pankova, k.kh.n. ass. Yu.Yu. Medvedev.
• Chemistry of acetylene and diacetile derivatives. Synthesis and transformations of functionalized diacetylene, Endsines, synthesis of new condensed heterocycles based on them. D.H.N., prof. I.A. Balova, Ph.D., prof. A.V. Vasilyev, Ph.D., Doc. I.A. Boyarskaya, N.A. Danilkin, V.N. Sorokumov, K.Kh.n., Art. prep. A.G. Lyapunova, K.Kh.n., Ass. V.N. Mikhailov.
• Hydrazine derivatives and polyazotist compounds. Aminoziridines. Aminonitren, Azomethinylides and reactions of 1,3-dipolar cycloprication. Three-, five- and six-membered nitrogen heterocycles. D.H.N., prof. MA Kuznetsov, K.Kh.n., Doc. A.S. Pankova.
• Asyridines, oxiranes, thiyran, tietany, amidines, sulfonamides and sultami. Aromatic and non-aromatic heterocyclic compounds containing nitrogen, sulfur and oxygen atoms. D.H.N., Assoc. V.V. Sokolov.
• Analysis of organic compounds of gas and liquid chromatography methods, capillary electrophoresis, chromatomass spectrometry, including research ambient, biological objects, pharmaceutical preparations. Analysis and separation of mixtures of biologically active compounds using highly efficient liquid and thin-layer chromatography, capillary zone electrophoresis, micellar electrokinetic chromatography, development of new organic analysis options for medical diagnostics purposes. Development of new methods of chromatographic and chromato-spectral identification of organic compounds, creating bases of analytical parameters. D.H.N, prof. IG Zenkevich, prof. L.A. Kartzova, K.Kh.n., Doc. E.A. Bessonova.

In more detail with the directions of research of various scientific groups, you can find

Ministry of Education and Science of the Russian Federation Federal Agency for Education Russian Chemical - Technological University named after D.I. Mendeleev Approve: Rector of the PCTU. D.I. Mendeleeva V.A. Kolesnikov "____" __________________ 2007. Course training program "Basics of biochemistry" Direction 550800 " Chemical Technology Biotechnology "for students of all chemical and technological specialties and students of the Chemical-Pedagogical Department (011000) The program is approved by the methodological section of the scientific council of the PCTU. DI. Mendeleev "____" __________________ 2007 Chairman Zhilin V.F. Moscow 2007 Explanatory note The course is intended for all students of the PCTU them. DI. Mendeleev, studying in the direction of "Chemical Technology and Biotechnology" and is a logical continuation of all chemical disciplines, which are studied by students in the first and second courses - theoretical foundations of chemistry, inorganic chemistry, analytical, physical and organic chemistry. The course introduces students with the basics of biochemistry - science on chemical processes occurring in living cells and organisms, as well as on biological substrates involved in these processes. The place of biochemistry and its addicted sections in the System of Sciences of Life, characterizes the relationship between biochemistry, organic and bioorganic chemistry. The use of biochemical knowledge in solving chemical-technological, engineering and environmental and social problems is illustrated. The main sections of the course are dedicated to the structure and functions of cells and cellular organelles, structure and biological functions Of most important biopolymers and bioregulators (proteins, nucleic acids, carbohydrates, lipids, vitamins, coenzymes, hormones). Much attention is paid to the processes specific for living systems: enzymatic catalysis, the exchange of carbohydrates, proteins and lipids, membrane transport, energy transformation, xenobiotics metabolism. The distribution of lecture and seminar watches (3-0-4) is given below. To monitor the course of the course, it is planned to conduct rating control work. The rate ends with a differentiated offset. The program is drawn up at the Department of Organic Chemistry. The program was prof. Purse V.F. prof. Lopin OD Exam or distribution of study clocks by courses Section 1 2 3 4 5 6 7 8 9 10 Name Introduction. The main provisions of the cytology of amino acids and proteins Enzymes and vitamins Carbohydrates Lipids nucleic acid metabolism and metabolism Energy biochemical cycles Bioregulators LEK. sem Lab. Himself. 2 2 2 2 4 5 2 9 4 2 9 4 2 7 3 1 5 3 1 5 2 2 6 5 3 10 5 3 8 Total 36 18 72 Course content 1. Introduction Biochemistry. Biochemistry relationship with related disciplines. Static biochemistry: learning chemical composition and the buildings of substances contained in living organisms. Dynamic biochemistry: study of metabolic processes as the basis for the activities of living organisms. Basic biochemistry methods. 2. The main provisions of cytology. Elements of cell theory. Procarniot and eukaryotes. Cellular organelles, their structure and functions: core, cytoplasm (ribosomes, mitochondria, lysosomes, endoplasmic reticulum, a complex of the Golges, hyaloplasm), a cell membrane and a cytoskeleton. The role of water in the vital cells of the cell. 3. Amino acids and proteins. Amino acids: Properties, classification, analysis methods. Peptide synthesis. Primary protein structure. Chemical properties and methods for determining the primary structure of proteins. Internal and intermolecular interactions that determine the spatial structure of proteins. Secondary, tertiary and quaternary structure. Protein functions. Denaturation of proteins. The effect of the hierarchical structure of proteins on their biological properties. Methods for the allocation and identification of proteins. Classification of proteins. The role of proteins in nutrition. 4. Enzymes and vitamins. Biomedical value of enzymes. Nomenclature and enzyme classification. Structure and catalytic properties of enzymes. Principles of enzymatic catalysis. Quantitative determination of enzymatic activity. The effect of temperature, pH, enzyme concentration and substrate at the rate of enzymatic reactions. Regulation of enzyme activity: Alosteric control, competitive and non-competitive inhibition, covalent modification and genetic control. Coofers and cofactors. Vitamins: Definition and classification. The structure of vitamins and their role in enzymatic reactions and in metabolic processes. Enzyme inhibitors as medicinal products. 5. Carbohydrates. Biomedicine carbohydrate value. Photosynthesis of carbohydrates. Classification of carbohydrates and their most important reactions. Deoxyshara and Aminosahara. Disaccharides and polysaccharides: lactose, maltose, sucrose, starch, glycogen, cellulose, chitin. The role of carbohydrates in nutrition. 6. Lipids. Biomedicine lipid value. Structure and classification of lipids. Saturated and unsaturated acids and their esters. Fats and oils. Glycerides and phosphoglycerides. Sphingolipid. Terpene and steroids. The structure and properties of cell membranes. Eicosanoids: Prostaglandins and leukotrienes. 7. Nucleic acids. Biological significance of nucleic acids. Deoxyribonucleic and ribonucleic acids. Nucleotides. Building and functions in living organisms. Reactions matrix synthesis and their meaning. Transfer of hereditary signs. Protein biosynthesis. Mutagenesis and hereditary diseases. Determination of the nucleotide sequence. Biotechnology and genetic engineering. Bioinformatics. 8. Metabolism and metabolism. The concept of metabolism and metabolic paths. Catabolism and anabolism. Metabolism of carbohydrates. Regulation of blood glucose (insulin and glucagon). Diabetes. Methods for analyzing blood glucose and urine. Metabolism of lipids. Storage and splitting of fats. Oxidation and biosynthesis of saturated acids. Metabolism of proteins and amino acids. The relationship of the exchange of proteins, carbohydrates and lipids. Problems of regulation of metabolism. Regulation and integration of metabolism in mammals. 9. Energy biochemical cycles. Enderganic and exerganic reactions in a living cell. Metabolism and biochemical energy production. The role of ATP in the exchange of energy. Metabolic pathways and conjugate reactions. Oxidized and restored forms of coenzymes. Cycle citric acid. Organization of the respiratory chain. Oxidative phosphorylation. Vitamins - antioxidants. 10. Bioregulators. Classification of bioregulators: hormones, neurotransmitters, medicines and xenobiotics. Hormones as chemical regulators of the endocrine system. Classification of hormones: protein hormones, steroid, derivative amino acids. Mechanisms of hormone action. Secondary messengers. Neurotransmitters - Chemical regulators nervous system. The mechanism of transmission of the nervous signal and the role of neurotransmitters. Adrenaline and Noradrenalin. Acetylcholine, its agonists and antagonists. Histamine and antihistamines. Serotonin, dopamine and antidepressants. Dopamine and narcotic dependence. Medicines and xenobiotics: mechanisms of action and metabolism. Basic literature: 1. Filippovich Yu.B. Basics of biochemistry.- M.: Aar, 1999 Additional literature: 1. Eliot V., Eliot D. Biochemistry and molecular biology, M. YBB Biomedical Chemistry Ramne, 1999. 2. Musil Ya., Novakova O., Kuntz K. Modern biochemistry in schemes. Ed. Peace, Moscow, 1981. 3. Colman Ya., Rem K.-g. Visual biochemistry. Ed. Mir, Moscow, 2000. 4. Linner A. Basics of biochemistry. Ed. World, Moscow, 1985, TT. 1-3.

History of the Department

The department of organic chemistry and high molecular weight compounds was formed in 2009 as a result of the compound of the department of organic chemistry and high molecular weight compounds.

Currently, 12 teachers work at the department: 6 doctors of sciences, professors, 6 candidates of science, associate professors and 5 people serving personnel, of which 3 candidates of Chemical Sciences.

Heads the Department of Hashirova S.Yu. The department preparations of students in the specialty "Fundamental and Applied Chemistry" specialization "Organic Chemistry", undergraduate "Chemical Technology", in the magistracy under the program "Chemical Technology", "High Molecular compounds".

To prepare highly qualified personnel in the field of synthesis, modifications, the study of the properties of high molecular compounds (polymers), graduate school and doctoral studies in the direction of the department are "high molecular compounds". Currently, at the Department of 2 doctoral students, 11 graduate students and 41 Master. Important importance in the training of specialists for the national economy has research work, which the department performs in 8 directions. The faculty professorship has repeatedly won the grants of various funds in contests.

The department regularly conducts All-Russian and international conferences, where the most active participation Students, masters, graduate students and doctoral students specializing in the department are accepted. The I-XI International Conference "New Polymer Composite Materials" with the participation of leading scientists of Russia. Conducted 1-6 All-Russian Conference "Nanostructures in polymers and nanocomposites", where the leading scientists of universities and institutes Russian Academy science Employees of the department are often traveling abroad to participate in international symposia and conferences (USA, France, Switzerland, Germany, Spain, Mexico). The department constantly supports connections with the PCTU. D. I. Mendeleev, FSUE NIIFHHI. Karpova, INEOS them. N.N. Nesmeyanova RAS, INCH them. A.V. Topciyeva RAS, Ivanovo University of Technology, which makes it possible to students, master, graduate students and doctoral students to carry out various studies.

Main activities

• In-depth study of the paths of optimization and intensification of the processes of the directional synthesis of macromolecules, and, consequently, the directional control of the complex properties of the synthesized polymers.
• The targeted synthesis of new condensation polymers of various buildings (macromolecular design).
• Directed regulation of the complex of valuable properties of synthesized polymers (high chemical, thermo- and heat resistance, large coke residue, good electrical properties, physicomechanical indicators, etc.).
• Development of technology for obtaining and administering various stabilizers (modifiers) in the polymer matrix. Evaluation of the stabilizing and modifying effect of additives on the main properties of polycondensation polymers in the melt and in the solid phase.
• Conducting a complex of physicochemical studies in order to aimed changing the relationship "Structure - Property", depending on the nature of modifiers.
• The synthesis of new polyelectrolytes and the study of the possibility of obtaining new biologically active and biocidal substances on them.
• Development of technology for obtaining new polymer composite nanomaterials based on water-soluble ionic polymers and layered silicates to create products with sorption and biocidal properties.
• Development of fireproof polymer composites and nanocomposites for the cable industry.
• Development of polymeric materials with elevated barrier properties.
• Development of the theoretical foundations and technologies for obtaining aromatic superconstruction polymers and composite materials based on them with elevated operational and technological characteristics.
• Development of new polymeric materials for digital design and production (3D printing).
• Creation together with the enterprises of the real sector of the economy of high-tech production of new polymer products based on the developed technologies.

Department composition:

1. Hashirova Svetlana Yuryevna - D.H.N., Head. Department of Organic Chemistry and High Molecular Couplings.
2. Bazheva Rimma Cahalovna - D.H.N., Professor of the Department of Organic Chemistry and High Molecular Compounds
3. Begiyev Madina Bilyallovna - D.Kh.n., Professor of the Department of Organic Chemistry and High Molecular Compounds
4. Borukaev Timur Abdulovich - D.Kh.n., Professor of the Department of Organic Chemistry and High Molecular Compounds
5. Kuchmenova Leana Hasanovna - K.Kh.n., Senior Lecturer of the Department of Organic Chemistry and High Molecular Compounds.
6. Musaev Yuri Israfilovich - D.H.N., Professor of the Department of Organic Chemistry and High Molecular Compounds
7. Musaeva Eleonora Borisovna - K.Kh.n., Associate Professor of the Department of Organic Chemistry and High Molecular Couplings.
8. Kharaev Arsen Muhamedovich - D.Kh.n., Professor of the Department of Organic Chemistry and High Molecular Compounds
9. I want Idris Yusufovich - K.Kh.n., Associate Professor of the Department of Organic Chemistry and High Molecular Compounds.
10. Ardasheva Almira Abdul-Kerimna - Engineer of the Department of Organic Chemistry and High Molecular Compounds
11. Gevorkova Arknaz Surenovna - Lead Engineer of the Department of Organic Chemistry and High Molecular Capacities
12. Kazancheva Fatimat Krymovna - K.Kh.n., Engineer of the Department of Organic Chemistry and High Molecular compounds
13. Karina Karina Ruslanovna - K.Kh.N., Engineer of the Department of Organic Chemistry and High Molecular Compounds
14. Haraeva Ruzanna Alekseevna - K.Kh.n., Engineer I Categories of the Department of Organic Chemistry and High Molecular Compounds

The department is published in the direction of preparation 18.03.01 - chemical technology, profile "Technology and processing of polymers", 04.05.01 Fundamental and applied chemistry, specialization "Organic Chemistry", 18.04.01 Chemical technology, Master's program "Technology and processing of polymers", 04.04.01 Chemistry, Master's program "High Molecular compounds".

Scientific research

The main directions and forms of activity.

Research activities: conducting scientific research on fundamental and applied directions in the field of chemistry and technology of high molecular compounds.

Innovative and innovative activities: solving applied problems, design development, implementation of research results in practice and educational process.

Educational activities: organization and provision of research work and training practices of students, undergraduates and graduate students of natural science faculties, provision of additional educational services by individual programs Retraining personnel and advanced training of specialists.

Priority directions of scientific and innovative activity are:

a) the fundamental problems of chemistry of high molecular compounds;

b) polymer nanocomposites and multilayer structures;

c) physicochemical methods for the study of polymer composites and nanomaterials;

d) modification and stabilization of polymeric materials;

e) recycling and disposal of polymer composite materials and products of them;

(e) Theoretical modeling of the structure and properties of polymer composite materials;

g) new polymeric materials: synthesis and properties.

Qualitative indicators of the department

Employees of the department published more than 2000 articles in foreign and domestic journals, 30 monographs were issued: 4 issued in the United States, one of them received funding, participating in the competition of the Russian Fund fundamental studies. According to the Profile of the Department, the Council on the Protection of Doctoral and PhD dissertations "High Molecular compounds". All conditions have been created at the department (scientific potential, material and technical base, the presence of instruments, graduate school, dissertation council, etc.) in order to pass the way from the student to Professor within the framework of the KBSU. The department has a scientific and educational center "Polymers and composites", the laboratory of progressive polymers. The staff of the department received a number of original scientific results In the field of polycondensation polymers of various classes that have received international recognition and supported in the FDP "Studies and Development on the Priority Directions of the Scientific and Technology Complex of Russia (GK No. 02.552.11.7079; No. 2.513.11.3158; No. 02.513.11.3219; No. 02.740.11.5121, No. 02.740.11.0798); An analytical departmental target program "Development of the scientific potential of higher education (2009-2010)" GK No. 2.1.1 / 3612; RFBR project (06-03-96641). The results of several projects made with the participation of KBSU on orders of organizations of the real sector of the economy are introduced at the enterprises of the industry. The technology of obtaining nanocomposite multilayer films from polyethylene is introduced on LLC "South Polymer" (Stavropol Terminal, Kislovodsk), the technology of obtaining polybutylenerthephthalate has been implemented on the RUE on Mogilevchimvolokno (Belarus). Works were successfully carried out on the creation of nanocomposite cable products with increased fire resistance together with Cable Plant Cable Plant "Caucasian" in the framework of the Resolution No. 218 of the Government of the Russian Federation under the Treaty No. 13.G25.31.0048 from September 7, 2010, together with Tankneti LLC, a project was implemented According to the "Development and development of high-tech and energy-efficient production of functional modifying composites and preforms of a new generation based on them for the manufacture of import-substituting environmental polyethylene terephthalate containers with increased barrier properties" (Agreement No. 02.g25.31.0008 from February 12, 2013).

Masters, graduate students and doctoral students of the Department have repeatedly received scholarships of the President of the Russian Federation and the CBD, received grants along the DAAD line, under the program "M.N.I.K.". During the existence of the department carrying out training on high-molecular compounds by the faculty led by the founder and head of the scientific school under the leadership of Mikitayev A.K. 35 doctors of science, more than 100 candidates of science prepared.